A New Fluorite Type Compound Pb5Bi17X5O43: Synchrotron and Neutron Structure Determination (X: P) and Conduction Properties (X: P, V and As).
β Scribed by Pascal Roussel; Sophie Giraud; Emmanuelle Suard; Jean-Pierre Wignacourt; Hugo Steinfink
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 90 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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The structures of Sr 1.25 Bi 0.75 O 3 and superconducting Sr 0.4 K 0.6 BiO 3 have been determined from synchrotron X-ray powder di4raction data between 4 K and the decomposition temperature, at 973 and 573 K, respectively. The symmetry remains monoclinic (a+(2a p , b+(2a p , c+2a p , +903, P2 1 /n s
The new compounds BiMn 2 PO 6 , BiMn 2 AsO 6 , and BiMn 2 VO 6 have been prepared and shown to be structurally related to several other BiA 2 MO 6 compounds. The structure of BiMn 2 PO 6 was refined from neutron powder diffraction data in space group Pnma with a=12.04 ( A, b=5.37 ( A, c=8.13 ( A, an
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