✦ LIBER ✦

A new fitting law for rotational energy transfer

✍ Scribed by B.J. Whitaker; Ph. Brechignac

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 494 KB
Volume: 95
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80583-1

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✦ Synopsis

A new fitting law for :he primary set of rate constants. .Q+_o, occurring in lOSA fxtorkation is prcscnted. Assuming thnt the interaction potential is donlioated by ZI single tern] of the Legendre polynonkd expansion. PA(cos 0). we find k~-,o = C[ (a/n) io_g(aht) -oh + I]. The two fitting parametersa and c are espressed in terms of the ran_re zmd strcr@b of the model potenrisl. The validity of this law is tested.

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