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A New Family of High-Dimensional Molecular Magnets Built from the Manganese−Azido System. Syntheses, Structures, and Magnetic Characterization of Two New Ferro−Antiferromagnetic Two-Dimensional Complexes

✍ Scribed by Escuer, Albert; Vicente, Ramon; Goher, Mohamed A. S.; Mautner, Franz A.

Book ID: 125910975
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 201 KB
Volume: 36
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic961476f

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## Abstract A series of homo‐ and heterometallic manganese(III or IV) clusters, [Mn~2~O~2~(pybim)~4~](NO~3~)~4~·11H~2~O [1; pybim = 2‐(2‐pyridyl)benzimidazole], [Mn~3~O~4~(bipy)~4~(H~2~O)~2~][Ce(NO~3~)~5~(H~2~O)][NO~3~]~2~·2H~2~O (2; bipy = 2,2′‐bipyridine), [Mn~2~Ce~3~O~6~(pta)~6~(NO~3~)~2~(dmf)~4