A new expression for the vibrational overlap integrals between arbitrary one-dimensional harmonic oscillators

✍ Scribed by Toshitaka Terasaka; Toshiki Matsushita

• Publisher: Elsevier Science
• Year: 1981
• Tongue: English
• Weight: 329 KB
• Volume: 80
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(81)80114-5

✦ Synopsis

4 new, compact formula for the vrbrational overlap integrals between two harmonic potentials with both arbitrary curvatures and equfiirium

positions is derived in a systematic manner with its several derivative formu&. Some mathematical propertres of the overlap integrals obtained are discussed * In ref. [3] computations by the use of eq. ( 22) have been apphed to the estimation of the vibrational matrix elements of nearadiabatic transitions and the results are listed in tables.