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A new expeditious synthesis of (+)-exo-brevicomin via efficient CC bond formation of triflates

✍ Scribed by Hiyoshizo Kotsuki; Isao Kadota; Masamitsu Ochi

Book ID
104229458
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
128 KB
Volume
30
Category
Article
ISSN
0040-4039

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Reaction of ffketo sulphones with 2N NaOH, at 70 \*C, in aqueous media and in presence of cetyttrimethylammonium chloride (CTACI), produces the C-C bond fission between the carbonyl group and the carbon bearing the sulphone.