A new enantiopure d-camphor-derived palladacycle
β Scribed by Dickmu, Gerard C.; Stahl, Lothar; Smoliakova, Irina P.
- Book ID
- 121505448
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- English
- Weight
- 562 KB
- Volume
- 756
- Category
- Article
- ISSN
- 0022-328X
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The enantiospecific preparation of two novel C10-S(II)-and C10-Se(II)-substituted camphor derivatives (arylsulfide and arylselenide) from readily available camphor is described. The established three-step route constitutes a model procedure for the straightforward preparation of interesting enantiop
A convenient synthesis of (-)-N-styryl-N- [2-(1,7,7-trimethyl-yl)ethanol (6). Cyclization of the N-formylenamine 2 with the aid of 9-borabicyclo[3.3.1]non-9-yl triflate yielded a methano-bicyclo[2.2.1]hept-2-enyl)ethyl]formamide (2) was developed starting from natural (+)-camphor (3) via (-)-2-(born