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A new efficient tetraphosphine/palladium catalyst for the Heck reaction of aryl halides with styrene or vinylether derivatives

✍ Scribed by Marie Feuerstein; Henri Doucet; Maurice Santelli

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
75 KB
Volume
43
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Heck reaction of aryl halides with linea
Heck reaction of aryl halides with linear or cyclic alkenes catalysed by a tetraphosphine/palladium catalyst
✍ Florian Berthiol; Henri Doucet; Maurice Santelli πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 115 KB

cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl(C 3 H 5 )] 2 system catalyses efficiently the Heck reaction of aryl halides with linear alkenes such as pent-1-ene, oct-1-ene or dec-1-ene. Selectivities up to 70% in favour of E-1-arylalk-1-ene isomers can be obtained. In the p