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A new double minimum problem: The B1Σ+ state of BH

✍ Scribed by J.C. Browne; E.M. Greenawalt

Book ID
103009502
Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
380 KB
Volume
7
Category
Article
ISSN
0009-2614

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✦ Synopsis

An extended configuration interaction calculation of the wavefunction and potential curve for the l3 LCf stnte of BH reveals that this state has a double minimum in its potential curve somewhat anaiogous to the E 3 Flz+ state of H2. Only tbc transitions to levels in the inner minimum have yet been observed spcctroscop tally. K Predictions are made of the position and spacings of vibrational levels in the outer minimum and nbove the maximum in the BIE+ potential curve.

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