A New Diazacyclooctane Dihydroxamate as a Siderophore Analogue − Synthesis and Equilibrium Studies of Iron(III) and Copper(II) Complexes
✍ Scribed by Margarida Gaspar; J. Paulo Telo; M. Amélia Santos
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 203 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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The electrochemical oxidation of anodic metals (iron and copper) in MeCN solutions of 2-pyridinone (HOPy), 1hydroxy-2-pyridinethione (HPT), 2-pyridinemethanethiol-1-oxide (HPMTO) or its dimer 2,2'-dithiodimethyldipyridine-l,l'-dioxide (PMTO)z, gave the simple complexes Fe(OPy)2" HzO, Cu(OPy)2" 3H20,
## Abstract The synthesis and magnetic behavior of four new dinuclear iron(II) complexes Fe~2~2a‐d × 4Py with the iron in an octahedral coordination sphere is presented in this paper. The complex **c** is a high‐spin complex over the whole temperature range investigated, while the complexes **a,b**