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A new cyclopendant organophosphorus complexone —1,4,7-tris(β-dihydroxyphosphorylethyl)-1,4,7-triazacyclononane

✍ Scribed by T. Ya. Medved'; M. I. Kabachnik; I. B. Goryunova; B. K. Shcherbakov; F. I. Bel'skii; P. V. Petrovskii; Yu. M. Polikarpov


Book ID
112449603
Publisher
Springer
Year
1988
Tongue
English
Weight
462 KB
Volume
37
Category
Article
ISSN
1573-9171

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Exchange interactions in a trigonal chro
✍ Hans Riesen; Hans U. Güdel; Phalguni Chaudhuri; Karl Wieghardt 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 315 KB

HigIl-resolution absorption, iuminesccnce, Zeeman and MCD experiments were performed cm sir& crystals of the title compound. The singlet-tripiet and trip&t-quintet exchange splittings in the ground state are 138 and 267 cm-'. respectively. The corresponding exchange parameters are 2J= -128 cm-' andj