A New Cycloaddition Process Involving Nitro Group Participation in Polynitroaromatic Chemistry
✍ Scribed by Hallé, Jean-Claude; Vichard, Dominique; Pouet, Marie-José; Terrier, François
- Book ID
- 126226289
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 147 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
The alcohol 12 reacted with 4-toluenesulfonyl chloride in boiling dichloromethane solution to give the chlorinated product 13 rather than the expected tosylate 3 by a mechanism that could involve neighbouring group participation of the nitro-substituent. In contrast, the isomeric alcohol 15 reacted