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A New Coupling Reaction of Vinyl Esters with Aldehydes Catalyzed by Organosamarium Compounds

✍ Scribed by Takeno, Mitsuhiro; Kikuchi, Shirou; Morita, Ken-Ichi; Nishiyama, Yutaka; Ishii, Yasutaka


Book ID
127351736
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
297 KB
Volume
60
Category
Article
ISSN
0022-3263

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α,ω-Dialkyl-substituted polyenes by pall
✍ Kiehl, Alfried ;Eberhardt, Anke ;Müllen, Klaus 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 897 KB

## Abstract α,ω‐Dialkyl‐substituted linear polyenes are synthesized in good yields by the palladium‐catalyzed coupling reaction of trialkyltin‐ and iodo‐substituted olefinic precursors. Central building blocks are the distannylated butadiene 8 and vinyl iodide 3. Our synthetic strategy was successf