A new correlation for saturated densities of liquids and their mixtures

✍ Scribed by Risdon W. Hankinson; George H. Thomson

• Publisher: American Institute of Chemical Engineers
• Year: 1979
• Tongue: English
• Weight: 940 KB
• Volume: 25
• Category: Article
• ISSN: 0001-1541
• DOI: 10.1002/aic.690250412

✦ Synopsis

Abstract

A new correlation has been developed for the densities of saturated liquids and their mixtures. The correlation is relatively easy to use and is applicable to a wide variety of liquids. The saturated liquid density correlation is flexible and consistent and requires only reduced temperature, acentric factor, and a characteristic volume for each pure compound. Mixing rules are given. When tested against a data base of 2 657 points of pure compound liquid density data for 97 hydrocarbons and 1 851 points for 103 other compounds, the new correlation gave an average absolute error of 0.37% compared to 2.14% for the Yen‐Woods correlation and 0.50% for the SDR equation as modified by Spencer and Danner. For 2 994 points of liquid mixture density data for 167 mixtures, the new correlation gave an average absolute error of 1.40% compared to 5.64% for the Yen‐Woods correlation and 2.95% for the SDR equation. Characteristic volumes are listed for 200 compounds; they are generalized as functions of acentric factor for various types of compounds and are compared to critical volumes.