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A new condensation synthesis of allenes and dienes

✍ Scribed by Reynolds, Kelly A.; Dopico, Pablo G.; Sundermann, Michael J.; Hughes, Karin A.; Finn, M. G.


Book ID
126245121
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
295 KB
Volume
58
Category
Article
ISSN
0022-3263

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A new radical synthesis of allenes
✍ BΓ©nΓ©dicte DelouvriΓ©; Emmanuel LacΓ΄te; Louis Fensterbank; Max Malacria πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 206 KB

The unprecedented radical 13-elimination of vinylsulfoxides opens a new access to functionalized di-and trisubstituted allenes. The radical precursors are obtained in two steps from a carbonyl derivative and a vinylsulfoxide. The radical translocation trick can also be used to trigger the 13eliminat