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A new compound constructed from Keggin anions and Cu-5,6-diamino-1,10-phenanthroline complexes: synthesis, structure, and characterization

✍ Scribed by Kong, Qing-Jiao; Hu, Mi-Xia; Chen, Ya-Guang


Book ID
126939105
Publisher
Taylor and Francis Group
Year
2011
Tongue
English
Weight
460 KB
Volume
64
Category
Article
ISSN
0095-8972

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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,