✦ LIBER ✦

A new class of polymer electrolytes based on chain-extended polyepoxides and LiClO4

✍ Scribed by L. Marchese; M. Andrei; A. Roggero; S. Passerini; P. Prosperi; B. Scrosati

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 421 KB
Volume: 37
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(92)80111-x

No coin nor oath required. For personal study only.

✦ Synopsis

Ahatract~hain-extended comb-like polyepoxides (PEP) with oligoethylene oxide units in the side chains have been synthesized and complexed with LiClO, to obtain a new class of polymer electrolyte. PEP/Li complexes showed conductivity up to 10T4S cm-' at room temperature. The influence of thermal properties, side chain length, content of diepoxide and salt concentration on conductivity was investigated. Finally the comparison between PEP/Li systems and similar polyvinylethers (PVE/Li) based membranes showed a significant improvement in conductivity with the polyepoxide structure in spite of negligible differences in complexes' Ts.

📜 SIMILAR VOLUMES

Characterisation of new polymer electrol

Characterisation of new polymer electrolytes based on polyethers and polyphosphazene blends

✍ José-Luis Acosta Luque; Enrique Morales Bergas 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 456 KB

This work reports the synthesis and characterisation of two new electrolytes based on polyethers (PEO and PPO) and polyphosphazene (PPz). In the structural study, the existence of new crystalline phases becomes apparent as a consequence of the co-ordination of the lithium salt (lithium triflate) and

Solid polymer electrolytes. XI. Preparat

Solid polymer electrolytes. XI. Preparation, characterization and ionic conductivity of new plasticized polymer electrolytes based on chemical-covalent polyether–siloxane hybrids

✍ Wuu-Jyh Liang; Ying-Pin Chen; Chien-Pang Wu; Ping-Lin Kuo 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB 👁 2 views

Synthesis and electrochemical characteri

Synthesis and electrochemical characterization of new polymer electrolytes based on dioxolane homo and co-polymers

✍ G. Goulart; J.-Y. Sanchez; M. Armand 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 361 KB

Several polyacetals have been investigated as host polymer, for polymer electrolytes. The cationic polymerization and copolymerixation of dioxolane @XL) and 4-methyl, dioxolane (MDXL) are reported. If PDXL is a semi-crystalline polymer, an amorphous polymer electrolyte at room temperature is obtaine

Solid Polymer Electrolytes Based on Ioni

Solid Polymer Electrolytes Based on Ionic Graft Polymers: Effect of Graft Chain Length on Nano-Structured, Ionic Networks

✍ J. Ding; C. Chuy; S. Holdcroft 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 307 KB 👁 1 views

Ionic conductivity and interfacial prope

Ionic conductivity and interfacial properties of polymer electrolytes based on PEO and boroxine ring polymer

✍ Yunsong Yang; T. Inoue; T. Fujinami; M. A. Mehta 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 2 views

A new Na+ ion conducting polymer electro

A new Na+ ion conducting polymer electrolyte based on (PEO+NaYF4) and its use as an electrochemical cell

✍ S Sreepathi Rao; M Jaipal Reddy; K Narasimha Reddy; U.V Subba Rao 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 242 KB