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A New Class of Optically Active Pyrrole Derivatives: (3R)-3-(Pyrrol-1-yl)alk-1-enes from D-α-Amino Acids.

✍ Scribed by Roberta Settambolo; Giuditta Guazzelli; Lucia Mengali; Alessandro Mandoli; Raffaello Lazzaroni


Publisher
John Wiley and Sons
Year
2003
Weight
114 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract The __García‐González__ reaction of D‐glucose and ethyl acetoacetate generated ethyl 5‐[(1′__S__)‐D‐erythrosyl]‐2‐methyl‐3‐furoate (**5**), which was converted to ethyl 5‐[(1′__R__)‐1′,4′‐dideoxy‐1′,4′‐imino‐D‐erythrosyl]‐2‐methyl‐3‐furoate (**3c**) and to ethyl 5‐[(1′__S__)‐1′,4′‐dideo