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A new class of isoquinoline alkaloids: The indenobenzazepines

✍ Scribed by Gábor Blaskó; S.Fazal Hussain; Alan J. Freyer; Maurice Shamma


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
213 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis


The dark yeZZou, indenobenzazepine alkaloids Zakorine (Ii and Zakoramine (21 have been found in fimaria parviflora Lam. (Fwnariaceael. In a transformation with biogenetic implications, treatment of the SpirobenzyZisoquinoZines dikydrofwnariZine (41 and dikydroparfumidine (71 with _ _ metkanesuZfony2 ckZoride and triethybnine in dry THF, followed by iodine oxidation, provided J_ and 2, re.spectiveZy.


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Dedicated to Professor I.Ribas on tze %asion of his 82nd birthday.