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A new class of inhibitors of secretory phospholipase A2: enolized 1,3-dioxane-4,6-dione-5-carboxamides

✍ Scribed by W Breitenstein; F Märki; S Roggo; I Wiesenberg; J Pfeilschifter; P Furet; E Beriger

Book ID
103629869
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
944 KB
Volume
29
Category
Article
ISSN
0223-5234

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A facile synthesis of 5-[(arylamino)(cya
A facile synthesis of 5-[(arylamino)(cyano)methylene]-2,2-dimethyl-1,3-dioxane-4,6-diones
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Treatment of 5-(4-chloro-5H-1,2,3-dithiazol-5-ylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione with primary arylamines in CH 2 Cl 2 at rt gave 5-[(arylamino)(cyano)methylene]-2,2-dimethyl-1,3-dioxane-4,6-diones in excellent yields. The latter compounds were utilized for the preparation of 2-cyano-4-quino