A New Class of Heterogeneous Platinum Catalysts for the Chemoselective Hydrogenation of Nitroarenes
✍ Scribed by Valerica Pandarus; Rosaria Ciriminna; François Béland; Mario Pagliaro
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 422 KB
- Volume
- 353
- Category
- Article
- ISSN
- 1615-4150
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In general, palladium ± carbon (Pd/C) catalyzed hydrogenation of epoxides affords the corresponding primary and secondary alcohols as a mixture. It has been found that the catalytic activity of a Pd/C ± ethylenediamine complex catalyst [Pd/C(en)] in the hydrogenolysis of epoxide functions is drastic
## Abstract A water‐tolerant bifunctional heterogeneous catalyst is able to effectively catalyse the selective hydrogenation of phenol to cyclohexanone in water at atmospheric pressure and room temperature with >99.9% selectivity to cyclohexanone at phenol conversions >99.9%. The catalyst was found
Various derivatives of (R)-1-(1-naphthyl)ethylamine have been synthesized and tested as chiral modifiers of Pt/alumina in the enantioselective hydrogenation of ketopantolactone. The best modifiers (ee up to 79%) possess an ester function in the a-position to the amino group. The modifiers performed