A new class of halogenated lactones from the red alga delisea fimbriata (bonnemaisoniaceae)
β Scribed by R. Kazlauskas; P.T. Murphy; R.J. Quinn; R.J. Wells
- Book ID
- 104243659
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 233 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Several species within genera of the family of red algae Bonnemaisoniaceae have yielded halogenated secondary metabolites. Halogenated heptan-2-ones were isolated from Bonnemaisonia hamifera' and two independent studies of geographically separate collections of Asparagopsis taxiformis 2,3 yielded haloacetones or haloforms respectively as major isolates whilst halobutenones were detected in both studies. We have found haloacetones, including the previously unreported l,l-dibromo-3-iodoacetone, together with bromoform in a freeze-dried sample of A.armata from Australian waters 4 but could detect
π SIMILAR VOLUMES
Our recent interest in the red alga Delisea fimbriata (Lamour.) (Bonnemaisoniaceae), stimulated by the absence of the usual epiphytic material, led to the isolation of a series of y-1actones.l
quai Ernest-Ansermet, CH-I 2 1 1 Geneva 4 (20.111.95) The absolute configuration of a series of naturally occurring and semi-synthetic halogenated furanones is proposed on the basis of chemical interconversions and X-ray and CD analyses. The CD analyses clearly reveal that the presence of the allyli