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A New Class of Benzoin Condensation Catalysts: N,N′-Disubstituted o-Phenylenediamines

✍ Scribed by Anatolii S. Morkovnik; Viktor N. Khrustalev; Sergei V. Lindeman; Yurii T. Struchkov; Zinaida S. Morkovnik

Book ID
111729661
Publisher
Royal Society of Chemistry
Year
1995
Tongue
English
Weight
227 KB
Volume
5
Category
Article
ISSN
0959-9436

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N,N-Dimethyl-and N,N-dibenzylalloxans la and lb have been prepared and used as novel dioxirane catalysts for the epoxidation of a range of di-and tri-substituted alkenes in good to excellent yield. The dibenzylalloxan lb can be recovered in high yield with no evidence of catalyst decomposition.