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A New Catalyst for the Reductive Elimination of Acylated Glycosyl Bromides to Form Glycals.

โœ Scribed by Robert V. Stick; Keith A. Stubbs; D. Matthew G. Tilbrook; Andrew G. Watts

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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Thiophosphoryl bromide: a new reagent fo
Thiophosphoryl bromide: a new reagent for the reduction of sulfoxides to sulfides
โœ I.W.J. Still; J.N. Reed; K. Turnbull ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 222 KB

Thiophosphoryl bromide (PSBrS) has been found to be a mild,effective reagent for the reduction of sulfoxides of widely differing structural types to the corresponding sulfides. \* A number of new procedures for the reduction of sulfoxides have recently been reportedIm6 and at least two excellent rev