In the presence of catalytic amounts of cobalt chloride and an amine (TMEDA, TEEDA, or DMF) the exclusive ฮฒ-hydrosilylation of acrylonitrile (Ia) and its 2-chloro derivative (Ib) can be achieved. -(CHAUHAN, MONI;
โฆ LIBER โฆ
A new catalyst for the efficient and selective .beta.-hydrosilylation of acrylonitrile. Effect of ultrasound
โ Scribed by Rajkumar, Amirthini B.; Boudjouk, Philip.
- Book ID
- 127327905
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 276 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0276-7333
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## Abstract The title reaction works particularly well for sterically encumbered propargylic alcohols and a single regioisomer obtained.