A New Biindenylidenedione Compound with Two Azobenzene Units: Synthesis and Photochromic Behavior Both in Solution and in the Solid State

A New Trinuclear Oxovanadium(V) Complex

A New Trinuclear Oxovanadium(V) Complex with DMPP Ligands − Synthesis and Structural Characterization in the Solid State and in Aqueous Solution

✍ Fernando Avecilla; Carlos F. G. C. Geraldes; M. Margarida C. A. Castro 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 416 KB 👁 2 views

A new trinuclear oxovanadium(V) complex with the anionic dmpp ligand (Hdmpp = 3-hydroxy-1,2-dimethyl-4-pyridinone), [V 3 O 6 (dmpp) 3 (H 2 O)](H 2 O) 2 , was isolated from the reaction of Hdmpp, KOH and sodium metavanadate at pH 4.5. The solid state structure of the [V 3 O 6 (H 2 O)(dmpp) 3 ](H 2 O)