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A New Bifunctional Asymmetric Catalysis: An Efficient Catalytic Asymmetric Cyanosilylation of Aldehydes

✍ Scribed by Hamashima, Yoshitaka; Sawada, Daisuke; Kanai, Motomu; Shibasaki, Masakatsu

Book ID
118195323
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
110 KB
Volume
121
Category
Article
ISSN
0002-7863

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The asymmetric cotalytic cyanosilylationof oliphaticaldehydes with Me3SiCN using (R)-BINOL-Ti(O-i-Pr)2 m an arymmem"c precakdyst is shown to proceed smoothly in dichloromethane to ~ford the cyanohydrinsin rekdvely high enantiose!ectivity (up @ 75~oee). @1997 Elsevier ScienceLtd. Recently,much inter

ChemInform Abstract: Asymmetric Catalyti
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v