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A New Aspect for the Insertion of the 16-Electron Species (η 5 -C 5 H 5 )ML into Saturated Hydrocarbons. A (η 5 -C 5 H 5 )ML + CH 4 (M = Rh, Ir; L = CO, SH 2 , PH 3 ) Case Study †

✍ Scribed by Su, Ming-Der; Chu, San-Yan

Book ID: 126422700
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 299 KB
Volume: 101
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp970021o

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📜 SIMILAR VOLUMES

Theoretical Model for Insertion of the 1

Theoretical Model for Insertion of the 16-Electron Species (η 5 -C 5 H 5 )M(L) into Saturated Hydrocarbons. A (η 5 -C 5 H 5 )M(CO) + CH 4 (M = Ru - , Os - , Rh, Ir, Pd + , Pt + ) Case Study

✍ Su, Ming-Der; Chu, San-Yan 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 251 KB

Density functional theory of CH bond act

Density functional theory of CH bond activation by transition-metal complex: A (η5-C5H5)ML (M=Rh, Ir; L=CH2, CO, SH2, PH3)+CH4 case study

✍ Ming-Der Su; San-Yan Chu 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 176 KB 👁 1 views

B3LYPrLANL2DZ calculations suggested that the singlet᎐triplet Ž .

Preparation and spectroscopic properties

Preparation and spectroscopic properties of a series of new bimetallic phosphine-bridged seven-coordinate complexes of the type [M4I4(CO)6L2(μ-L L] {M = Mo or W; L = PPh3, AsPh3 or SbPh3; L L = Ph2P(CH2)nPPh2 (n = 1, 2 or 4); L L = [Fe(η5-C5H4PPh2)2]}

✍ Paul K. Baker; Marit van Kampen; Dafydd ap Kendrick 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 361 KB

Photochemical studies as a function of s

Photochemical studies as a function of solvent viscosity. A new photochemical pathway in the reaction of (η5-C5H4Me)2Mo2(CO)6 with CCl4Electronic supplementary information (ESI) available: plots of quantum yields vs. viscosity for the photolysis of Cp′2Mo2(CO)6 in hexane–squalane, hexane–paraffin oil, THF–polyglyme, and ethanol–propylene glycol; table of quantum yields showing dependence on [CCl4]; table of values of fitting parameters in eqn. (3). See http://www.rsc.org/suppdata/pp/b2/b202112a/

✍ Braden, Dale A.; Parrack, Eileen E.; Tyler, David R. 📂 Article 📅 2002 🏛 Royal Society of Chemistry 🌐 English ⚖ 109 KB