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A New Approach Towards the Synthesis of 3-Amino-6-(hetero)arylpyridazines Based on Palladium Catalyzed Cross-coupling Reactions

✍ Scribed by Bert U.W Maes; Guy L.F Lemière; Roger Dommisse; Koen Augustyns; Achiel Haemers

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
96 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis

The synthesis of 3-amino-6-(hetero)arylpyridazines via palladium catalyzed cross-coupling reactions (Suzuki, Stille) on 3-amino-6-chloropyridazine (1a) and 3-amino-6-iodopyridazine (1b) has been investigated. Comparison of the results shows that there is no need to start from 1b. An improved method for the synthesis of compound 1b from 1a is also described.

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