Upon treatment with [Mo(CO) ,I, 3-phenyl-4,5-hexamethyleneisoxazole undergoes an inclusion of acetylenic ester across the C4-C5 bond and elimination of an oxygen atom leading to [6](2,5)pyridinophane derivative.
A new approach to the biocyclo (5.2.1) decane system.
β Scribed by Yu.E. Klimko; S.D. Isaev; A.G. Yurchenko; O.S. Chizov
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 112 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
A simple route to the bicycle ( 5.2.1 > decane system by oxidation of trimethylenenorbornane is demonstrated.
π SIMILAR VOLUMES
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## Abstract A general method for the synthesis of unsubstituted and Cβ7βsubstituted azabicyclo[4.4.0]decane dipeptides (**23**, **30a**, and **30b**) that can serve as dipeptide mimetics has been developed. The key step of this new method involves the coupling reaction of the oxazolidine aldehyde *
## Abstract The photoaddition **6**β**7**, followed by a reductive cleavage of the ββchlorocyclobutylketone **7**, gave the stereochemically pure spiro [4,5]decane **8**.