A New Approach to the Bicyclo[4.3.0] Ring System of Natural Products from the Liverwort: Total Synthesis of (.+-.)-Chiloscyphone (I) and (.+-.)-Isochiloscyphone (II).
β Scribed by Junichi Shiina; Shigeru Nishiyama
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 12 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The functionalized tricyclic framework (XI) of the diterpene forskolin is synthesized by an intramolecular Diels-Alder reaction of the dienyne (VII), which is obtained by stereoselective introduction of the C side chains at C-1 and C-2 of tri-O-acetyl-D-galactal (I) via C-Ferrier and Claisen-Ireland
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