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A new approach to controlling catenated structures

✍ Scribed by David B. Amabilino; J. Fraser Stoddart

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
227 KB
Volume
112
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

A [2]catenane comprised of a macrocyclic polyether, analagous to bisparaphenylene 34‐crown‐10 ‐ but incorporating catechol units in its tetraethyleneglycol chains – and the cyclobis(paraquat‐p‐phenylene) tetracation, has been self‐assembled and shown to exist in solution as a non‐equimolar mixture of translational isomers.

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