Glycosylidene Carbenes a new approach to
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Karin Briner; Andrea Vasella
📂
Article
📅
1989
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John Wiley and Sons
🌐
German
⚖ 858 KB
A new approach towards the synthesis of glycosides based upon a (formal) insertion of glycosylidene carbenes into 0-H bonds is presented. The synthesis and characterization of the glycosylidene-derived diazirines 25-28, precursors of glycosylidene carbenes, are described. The diazirines were prepare