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A new and versatile route for the synthesis of highly substituted benzenoids

✍ Scribed by Jeffrey A. Robl


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
261 KB
Volume
31
Category
Article
ISSN
0040-4039

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Acylnitrilium ions. Versatile new interm
✍ Gregory Luedtke; Mark Westling; Tom Livinghouse πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 1003 KB

Acylnitrilium ions, generated by the exposure of tu-ketoimidoyl chlorides to AgBF, readily engage suitably disposed sites of molecular unsaturation in cyclization reactions leading to heterocyclic ring systems. This novel method for annulation is applicable to the construction of 5, 6, and 7 membere