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A new and mild synthesis of β-amino acids from masked β-enamino acid derivatives

✍ Scribed by Santos Fustero; Ma Dolores Díaz; Antonio Navarro; Esther Salavert; Enrique Aguilar

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
240 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

A new method of synthesis of racemic 13-amino acids 6 by reduction of masked N-substituted and Nunsubstituted I~-enamino acid derivatives 4 via C-protected B-amino acids 5 is described. The process occurs with high yields, total chemoselectivity and moderate diastereoselectivity. Readily available starting materials, inexpensive reagents and mild conditions are used to furnish derivatives 5 and 6.

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