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A new and efficient electrochemical ring opening of 7-oxanorbornene systems via a modified Ritter reaction: direct approach to bicyclic valienamine analogues

✍ Scribed by David Le Goanvic; Marie-Christine Lallemand; François Tillequin; Thierry Martens


Book ID
104230945
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
62 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


Electrogenerated acids (EGA), produced by controlled potential electrolysis in acetonitrile at a platinum electrode, permitted the oxa-ring opening and the acetamidation of the 7-oxanorbornene system of 4. It opens in one step a new route to bicyclic valienamine analogues 3.