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A new and efficient Baeyer–Villiger rearrangement of flavanone derivatives by the methyltrioxorhenium/H2O2 catalytic system

✍ Scribed by Roberta Bernini; Enrico Mincione; Manuela Cortese; Giovanni Aliotta; Anna Oliva; Raffaele Saladino

Book ID: 104231066
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 70 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01005-x

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✦ Synopsis

The catalytic Baeyer-Villiger rearrangement of flavanones is described by the use of the homogeneous methyltrioxorhenium (MTO)/H 2 O 2 system. In these experimental conditions 3,4-dihydro-4-phenyl-1,5-benzodioxepin-2-ones and previously not reported para-quinone derivatives have been obtained in mild experimental conditions from acceptable to good yields.

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