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A New and Easy Method for the Synthesis of 2-ARYL-3-ALKYL-7-NITRO-1,4-Benzoxathiin-4,4-Dioxides

✍ Scribed by Song, Cao; Ailong, Fan; Ziming, Huang; Zheng, Zhang


Book ID
121378189
Publisher
Taylor and Francis Group
Year
1996
Tongue
English
Weight
306 KB
Volume
26
Category
Article
ISSN
0039-7911

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A new approach for the synthesis of some
✍ Ai-Long Fan; Song Cao; Zheng Zhang πŸ“‚ Article πŸ“… 1997 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 268 KB

A series of 1,4-benzoxathiin 4,4-dioxide derivatives have been prepared by a new synthetic route. The reactions of 2-chloro-4-nitrobenzenethiol 1 with 1 -aryl-2-chloroethanones 2 in the presence of sodium hydroxide give 1-aryl-2-(2-chloro-4-nitrophenylthio)ethanones 3 which on oxidation with \(30 \%