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A new and direct access to glycono-1,4-lactones from glycopyranoses by regioselective oxidation and subsequent ring restriction

✍ Scribed by Isabelle Isaac; Imane Staslk; Daniel Beaupère; Raoul Uzan


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
215 KB
Volume
36
Category
Article
ISSN
0040-4039

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A New Efficient Access to Glycono-1,4-lactones by Oxidation of Unprotected Itols by Catalytic Hydrogen Transfer with RhH(PPh 3 ) 4 -Benzalacetone System. -Pentitols and hexitols which possess a plane of symmetry, e.g. (I), or a C-2 symmetry axis, e.g. (III), lead, with good yields, to the correspon