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A new and Convenient Route to the Amine-Boranes

✍ Scribed by Ashby, Eugene C.; Foster, Walter E.

Book ID
121812137
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
226 KB
Volume
84
Category
Article
ISSN
0002-7863

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## Abstract Pd‐Catalyzed amination of 3,5‐dibromo‐ and 3,5‐dichloropyridine (**1a** and **1b**, resp.) with linear polyamines **2** leads to the formation of a new family of pyridine‐containing macrocycles **3** with an ‘__exo__’‐oriented pyridine N‐atom (__Schemes 1__ and __2__). The dependence of