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A new and convenient process for preparation of optically pure arly 2-pyridyl sulfoxides

โœ Scribed by Tadao Shibutani; Hisashi Fujihara; Naomichi Furukawa


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
147 KB
Volume
32
Category
Article
ISSN
0040-4039

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Reaction of amines with di-2-pyridyl thionocarbonate affords the corresponding isothiocyanates at room temperature, while reaction of N,N'-disubstituted thioureas with di-2-pyridyl thionocarbonate in the presence of 4-dimethylaminopyridine as a catalyst affords the corresponding carbodiimides in hig