✦ LIBER ✦
A new alkyl peroxovanadium catalyst for selective oxidation of nitriles to α-oxo nitriles: A functional mimic of Cyt-P.450
✍ Scribed by B.M. Choudary; P.N. Reddy
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 325 KB
- Volume
- 112
- Category
- Article
- ISSN
- 1381-1169
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✦ Synopsis
Alkyl peroxovanadium complex catalysed functionalisation of methylene of benzyl cyanides to afford peroxo nitriles or aroyl cyanides selectively depending on the molar quantities of oxidant, tert butyl hydroperoxide (t-BuOOH) used is described for the first time.