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A New 2H-Azirin-3-amine as a Synthon for α-Methyl Glutamate.

✍ Scribed by Florentine M. Hilty; Kathrin A. Brun; Heinz Heimgartner

Publisher
John Wiley and Sons
Year
2005
Weight
28 KB
Volume
36
Category
Article
ISSN
0931-7597

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A Novel 2H-Azirin-3-amine as a Dipeptide
A Novel 2H-Azirin-3-amine as a Dipeptide (Aib-Hyp) Synthon
✍ Roland A. Breitenmoser; Thomas R. Hirt; Roeland T. N. Luykx; Heinz Heimgartner 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 104 KB 👁 2 views

The synthesis of methyl (2S,4R)-4-(benzyloxy)-N-(2,2-dimethyl-2H-azirin-3-yl)prolinate ( 10), a novel 2Hazirin-3-amine (3-amino-2H-azirine), is described (Scheme 1). The reaction of methyl (2S,4R)-N-(2methylpropanoyl)-4-(benzyloxy)prolinate ( 7) with Lawesson reagent gave methyl (2S,4R)-4-(benzyloxy