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A new [2 + 3] annulation for highly functionalized dihydrofurans via carbon-carbon bond formation

✍ Scribed by Hudlicky, Tomas; Barbieri, Graciela


Book ID
125974927
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
387 KB
Volume
56
Category
Article
ISSN
0022-3263

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Spiro-annulated cyclohexa-2,5-dienones v
✍ Gary W. Morrow; John S. Swenton πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 243 KB

Intramolecular trapping of the reactive intermediate from anodic oxidation of 2'.alkenyl substituted p-aryl phenols, followed by solvent capture, affords 4aryl-4-alkyl-cyclohexa-2,5-dienones. Anodic addition reactions of oxygen nucleophiles to aromatic substrates serve as useful routes to oxygenated