A neutron diffraction study of H, Na-Y zeolites
✍ Scribed by Z. Jirák; S. Vratislav; V. Bosáček
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 706 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-3697
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Structure of the layered oxide, LiNi 0.8 Mn 0.2 O 2 , was determined by TOF neutron powder diffraction using space group R3 m. Its ionic distribution was determined to be [Li 0.956 Ni 0.044 ] 3a -(Ni 0.791 Mn 0.209 ) 3b O 2 . Slightly higher temperature of the synthesis caused the disordered arrange
tion of the =SF, group by 90" relative to the =C(CF,), group is 91 kJ mol-' higher; this provides a qualitative idea of the amount of C-S double bonding, which was calculated to be approximately 122 kJ mol-' for alkylidene sulfur tetrafluorides.['I The calculation could also be performed for the is