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A Neutral, Water-Soluble Olefin Metathesis Catalyst Based on an N-Heterocyclic Carbene Ligand.

✍ Scribed by Justin P. Gallivan; Jason P. Jordan; Robert H. Grubbs

Publisher
John Wiley and Sons
Year
2005
Weight
16 KB
Volume
36
Category
Article
ISSN
0931-7597

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A Highly Active Water-Soluble Cross-Coupling Catalyst Based on Dendritic Polyglycerol N-Heterocyclic Carbene Palladium Complexes
✍ Markus Meise; Rainer Haag 📂 Article 📅 2008 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 247 KB

## Abstract __A new water‐soluble polyglycerol derivative functionalized with N‐heterocyclic carbene palladium complexes was prepared and applied as catalyst for Suzuki cross‐coupling reactions in water. The complex displays a metal loading of around 65 metal centers per dendrimeric molecule, which