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A nesting conformation of the 5′-bromo-1′,3′-xylyl-18-crown-5·tert-butylammonium hexafluorophosphate complex; the correlation of the structures of crown ether complexes in the solid state and in solution.

✍ Scribed by D.N. Reinhoudt; H.J. den Hertog Jr; F. de Jong


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
251 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis


Single-crystal X-ray analysis of the 5'-bromo-l',3'-xyly~-l8-crown-5*


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## Abstract Two neutral complexes [(L~6~^3^4M)Fe~2~Cl~4~]·2H~2~O·2CHCl~3~ (1) and [(L~6~^3^4M)Mn~2~Cl~4~]·CH~3~CN (2) have been synthesized {L~6~^3^4M = __N__,__N__,__N′__,__N′__‐tetrakis[(6‐methyl‐2‐pyridyl)methyl]propane‐1,3‐diamine} and their molecular structures established by X‐ray crystallogr