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A N-heterocyclic carbene derived highly regioselective ambident C–C–S and C–C–N 1,3-dipolar system

✍ Scribed by Liu, Mei-Fang; Wang, Bo; Cheng, Ying


Book ID
126494388
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
301 KB
Volume
11
Category
Article
ISSN
1359-7345

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## Abstract Arylnitroso compounds **1–3** easily reacted with dimethyl bromomalonate to give the corresponding __N__‐aryl‐__C,C__‐dimethoxycarbonylnitrones (**4–6**). Treatment of __C,C__‐dimethoxycarbonyl‐__N__‐( 1‐naphthyl)nitrone (**4**) with acetylene compounds (dimethyl acetylenedicarboxylate,