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A mössbauer investigation of oxidized Fe4S4 HiPIP II from Ectothiorohodospira halophila

✍ Scribed by Ivano Bertini; Antonio P. Campos; Miguel Teixeira; Claudio Luchinat


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
491 KB
Volume
52
Category
Article
ISSN
0162-0134

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Ferrites of the formula \(\mathrm{Mo}_{4} \mathrm{Fe}_{3-}, \mathrm{O}_{4}\), prepared by a soft-chemistry route, show mixed valence states of both iron and molybdenum cations. Mössbauer studies show that \(\mathrm{Fe}^{2+}\) and \(\mathrm{Fe}^{3+}\) ions are present on hoth the \(\mathrm{A}\) and \