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A monoclinic polymorph of catena-poly[[[diaqua­(pyridine-2-carboxamide-κ2N1,O)copper(II)]-μ-sulfato-κ2O:O′] monohydrate]

✍ Scribed by Xie, Hong-Zhen ;Pan, Wei-Juan

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
197 KB
Volume
63
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 291 K Mean (C-C) = 0.003 A R factor = 0.025 wR factor = 0.069 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title polymer, [Cu(C 7 H 3 NO 4 )(H 2 O) 2 ] n , the Cu II ion is pentacoordinated and exhibits a distorted square-pyramidal environment formed by one N atom and two O atoms from pyridine-2,4-dicarboxylate ligands and two O atoms from coordinated water molecules. Each pyridine-2,4-dicarboxyla

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In the title polymeric complex, [Cd(C 4 H 2 O 4 )(C 12 H 8 N 2 )-(H 2 O) 2 ] n , the Cd II ions are bridged by fumarate dianions to form zigzag complex chains.stacking is observed between the parallel phenanthroline ligands of neighboring complex chains. The Cd ion is located on a twofold axis and h