A molecular simulation approach to the prediction of the morphology of self-assembled nanoparticles in diblock copolymers
✍ Scribed by Posocco, Paola; Posel, Zbyšek; Fermeglia, Maurizio; Lísal, Martin; Pricl, Sabrina
- Book ID
- 120340160
- Publisher
- Royal Society of Chemistry
- Year
- 2010
- Tongue
- English
- Weight
- 566 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0959-9428
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Diblock copolymers of a-methylstyrene and isoprene were synthesized anionically. The morphology of the copolymers and of their blends with the homopolymers was studied by transmission electron microscopy. Based on this, a scheme is proposed to predict the morphological behavior associated with the b
## Abstract Real‐space self‐consistent field theory (SCFT) is employed to study the effect of solvent molecular size on the self‐assembly of amphiphilic diblock copolymer in selective solvent. The phase diagrams in wide ranges of interaction parameters and solvent molecular size were obtained in pr
## Abstract Reported here is self‐assembly behavior in selective solvent of diblock copolymers with relatively long corona‐forming block compared to core‐forming block. Three diblock copolymers, poly(ethylene glycol) monomethyl ether‐__b__‐poly(methacryloyl‐L‐leucine methyl ester), also denoted as